Table66:ListofSspecies
FACT
SUPCRT
LLNL
JNC-TDB
S[2-], S
2
[2-],
S
3
[2-], S
4
[2-],
S
5
[2-], HS[-],
H
2
S(aq), SO
2
(aq),
SO
3
[2-], SO
4
[2-],
S
2
O
3
[2-], S
2
O
4
[2-],
S
2
O
5
[2-], S
2
O
6
[2-],
S
2
O
8
[2-], S
3
O
6
[2-],
S
4
O
6
[2-], S
5
O
6
[2-],
HSO
3
[-], HSO
4
[-],
HS
2
O
4
[-], H
2
S
2
O
4
(aq), S(s)S(s2),
SO
3
(s)
S
2
[2-], S
3
[2-],
S
4
[2-], S
5
[2-],
HS[-], H
2
S(aq),
SO
2
(aq), SO
3
[2-],
SO
4
[2-], S
2
O
3
[2-],
S
2
O
4
[2-], S
2
O
5
[2-],
S
2
O
6
[2-], S
2
O
8
[2-],
S
3
O
6
[2-], S
4
O
6
[2-],
S
5
O
6
[2-], HSO
3
[-],
HSO
4
[-], HS
2
O
4
[-],
H
2
S
2
O
4
(aq), HSO
5
[-
], HS
2
O
3
[-],
H
2
S
2
O
3
(aq), S(Sulfur)
SO
4
[2-], HS[-],
H
2
S(aq),
H
2
SO
4
(aq), HSO
4
[-],
S[2-], S
2
[2-],
S
3
[2-], S
4
[2-],
S
5
[2-], S
6
[2-],
Sulfur(rhmb),
H
2
S(g), S
2
(g)
SO
4
[2-], S[2-],
SO
3
[2-], S
2
O
3
[2-],
HS[-], H
2
S(aq),
HSO
3
[-], HS
2
O
3
[-],
H
2
SO
3
(aq), HSO
4
[-],
S(c), S(g), S
2
(g),
SO
2
(g), H
2
S(g)
HATCHES
SO
4
[2-], HS[-],
S
2
[2-], S
3
[2-],
S
4
[2-], S
5
[2-],
SO
2
(aq), H
2
S(aq),
H
2
S
2
O
3
(aq),
H
2
S
2
O
4
(aq),
H
2
SO
3
(aq), HS
2
O
3
[-],
HS
2
O
4
[-], HSO
3
[-],
HSO
4
[-], S[2-],
S
2
O
3
[2-], S
2
O
4
[2-],
S
2
O
5
[2-], S
2
O
6
[2-],
S
2
O
8
[2-], S
3
O
6
[2-],
S
4
O
6
[2-], S
5
O
6
[2-],
SO
3
[2-], S(c),
Sulfur-rhmb
219
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7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
HSO
4
[-]
H
2
S(aq)
SO
4
[2-]
HS[-]
S[2-]
HSO
4
[-]
H
2
S(aq)
SO
4
[-]
HS[-]
S (FACT/FACTSAGE)
S (SUPCRT/FLASK-AQ)
S (LLNL/GWB)
S (JNC-TDB/GWB)
SO
4
[2-]
HS[-]
H2S(aq)
HSO
4
[-]
S[2-]
HSO
4
[-]
H
2
S(aq)
SO
4
[-]
HS[-]
Figure106: Eh-pHdiagramsofthesystemS-O-H(1).
S=10
−10
,298.15K,10
5
Pa.
220
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7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
SO
4
[2-]
HSO
4
[-]
H
2
S(aq)
HS[-]
S[2-]
S (HATCHES/FLASK-AQ)
Figure107: Eh-pHdiagramsofthesystemS-O-H(2).
S=10
−10
,298.15K,10
5
Pa.
221
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222
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Table67:ListofSbspecies
FACT
SUPCRT
LLNL
JNC-TDB
SbO
2
[-], HSbO
2
(aq),
SbO[+], Sb(s),
SbO
2
(s), Sb
2
O
3
(s),
Sb
2
O
3
(s2), Sb
2
O
4
(s),
Sb
2
O
5
(s)
SbO
2
[-], HSbO
2
(aq)
Sb(OH)
3
(aq),
Sb(OH)
5
(aq)
Sb(OH)
6
[-],
Sb
12
(OH)
64
(aq)
Sb
12
(OH)
65
[5-],
Sb
12
(OH)
66
[6-],
Sb
12
(OH)
67
[7-],
Sb[3+],        
SbOH[2+],
Sb(OH)
2
[+]
Sb(OH)
4
[-],
Sb
2
(OH)
6
(s)    
Sb(c),
Valentinite,
Sb
2
O
5
(s)
HATCHES
Sb(OH)
3
(aq),
Sb[3+], Sb(OH)
2
[+],
Sb(OH)
4
[-], Sb
2
O
3
223
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7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
HSbO
2
(aq)
SbO
2
[-]
Sb(s)
SbO[+]
HSbO
2
(aq)
SbO
2
[-]
Sb
2
O
4
(s)
Sb
2
O
5
(s)
Sb (FACT/FACTSAGE)
Sb (SUPCRT/FLASK-AQ)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
Sb (LLNL/GWB)
Sb (JNC-TDB/GWB)
NO DATA
Sb(OH)
3
(aq)
Sb(OH)
5
(aq)
Sb(OH)
6
[-]
Sb(OH)
2
[+]
Sb(OH)
4
[-]
Sb(c)
Figure108: Eh-pHdiagramsofthesystemSb-O-H(1).
Sb=10
−10
,298.15K,10
5
Pa.
224
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7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
Sb[3+]
Sb(OH)
3
(aq)
Sb(OH)
4
[-]
Sb (HATCHES/FLASK-AQ)
Figure109: Eh-pHdiagramsofthesystemSb-O-H(2).
Sb=10
−10
,298.15K,10
5
Pa.
225
Table68: ListofScspecies
FACT
SUPCRT
LLNL
JNC-TDB
Sc[3+], ScOH[2+],
Sc(s)Sc(s2),
Sc
2
O
3
(s), Sc(OH)
3
(s)
Sc[3+], ScOH[2+],
ScO[+], HScO
2
(aq),
ScO
2
[-]
226
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
7
9
11
13
5
3
1
0.0
-0.2
-0.4
-0.6
-0.8
0.2
0.4
0.6
0.8
1.0
1.2
pH
Eh(V)
Sc[3+]
ScOH[2+]
Sc
2
O
3
(s)
Sc[3+]
ScO[+]
HScO
2
(aq)
ScO
2
[-]
Sc (FACT/FACTSAGE)
Sc (SUPCRT/FLASK-AQ)
Sc (LLNL/GWB)
Sc (JNC-TDB/GWB)
NO DATA
NO DATA
Figure110: Eh-pHdiagramsofthesystemSc-O-H.
Sc=10
−10
,298.15K,10
5
Pa.
227
228
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