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CHEMCAD 
USER’S GUIDE 
CC-STEADY STATE 
And 
CC-BATCH 
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CC-STEADY STATE V
ERSION 
5.6 
TABLE OF CONTENTS 
Getting Started CHEMCAD Suite...............................................................................................................1 
How to Install CHEMCAD Suite for Windows.............................................................................................2 
What’s in the Box .........................................................................................................................2 
Basic Requirements.....................................................................................................................2 
Installing CHEMCAD Suite for Windows......................................................................................2 
Licensing Issues .........................................................................................................................8 
Selecting a License......................................................................................................................9 
Updating Your License.................................................................................................................9 
License Update: Reprogramming a Local Dongle......................................................................10 
Updating a Scribe Dongle...........................................................................................................10 
Updating a SuperPro Dongle......................................................................................................11 
License Update: Reprogramming a Network Dongle.................................................................11 
Updating a Netsentinel Dongle...................................................................................................12 
Updating a Superpronet Dongle.................................................................................................13 
Updating a Network License Manager.......................................................................................14 
Using This Manual with CHEMCAD..........................................................................................................14 
How to Use the Mouse.............................................................................................................................14 
How to Use the Keyboard in CHEMCAD..................................................................................................15 
Using Dialog Boxes..................................................................................................................................15 
Moving Around the Dialog Box...................................................................................................15 
Making Choice Box Selections...................................................................................................16 
Making List Box Selections.........................................................................................................16 
Character Fields in Dialog Boxes...............................................................................................16 
Closing a Dialog Box..................................................................................................................16 
Exiting a Dialog Box Without Savings Its Contents....................................................................16 
Selecting Object........................................................................................................................................17 
Selecting Streams and UnitOps for Plotting, Viewing, and Sizing..............................................17 
Selecting More Than One Object at a Time...............................................................................17 
Using Word and WordPad Documents Created by CHEMCAD...............................................................18 
An Overview of the Most Important CHEMCAD Windows........................................................................19 
The Top Level Window...............................................................................................................19 
The Simulation Flowsheet Window............................................................................................21 
The Plot Window .......................................................................................................................23 
Using the Tool Bar Buttons .......................................................................................................................24 
How to Print in CHEMCAD .......................................................................................................................26 
How to Print Tabular Output.....................................................................................................................27 
Briefly.........................................................................................................................................27 
Details........................................................................................................................................27 
How to Print Graphical Outputs and Displays...........................................................................................28 
Briefly.........................................................................................................................................28 
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File Management in CHEMCAD...............................................................................................................29 
The CHEMCAD File Types........................................................................................................29 
Where Files are Stored..............................................................................................................29 
Importing Jobs............................................................................................................................30 
Exporting Jobs...........................................................................................................................30 
Save as Case.............................................................................................................................31 
Using Help................................................................................................................................................31 
To Find a Topic in Help..............................................................................................................31 
To Copy Information from a Help Topic.....................................................................................32 
To Print a Help Topic.................................................................................................................32 
To View a List of Topics You’ve Seen........................................................................................32 
To Search for Words or Phrases................................................................................................33 
To Customize the Search for Words or Phrases........................................................................33 
CC-STEADY STATE TUTORIAL.............................................................................................................34 
Introduction...............................................................................................................................................34 
Basic Rules – General..............................................................................................................................34 
How to Use the Mouse.............................................................................................................................35 
Using the Keyboard..................................................................................................................................35 
The Tool Bar Buttons...............................................................................................................................35 
A Description of the Problem....................................................................................................................36 
Getting Started.........................................................................................................................................37 
Starting a New Job – The Simulation Window..........................................................................................38 
Selecting Engineering Units.....................................................................................................................40 
Drawing the Flowsheet.............................................................................................................................42 
Putting Streams on the Flowsheet............................................................................................................49 
Selecting Components.............................................................................................................................51 
Selecting Thermodynamic Options...........................................................................................................54 
Defining the Feed Streams ......................................................................................................................56 
Inputting Equipment Parameters..............................................................................................................58 
Running the Simulation............................................................................................................................61 
Reviewing the Results Interactively..........................................................................................................61 
Re-Running the Simulation ......................................................................................................................65 
Producing a Report..................................................................................................................................67 
Generating the Process Flow Diagram.....................................................................................................70 
Summary..................................................................................................................................................74 
CC-BATCH TUTORIAL...........................................................................................................................75 
Introduction...............................................................................................................................................75 
Basic Rules – General..............................................................................................................................75 
How to Use Mouse...................................................................................................................................76 
Using the Keyboard..................................................................................................................................76 
The Tool Bar Buttons...............................................................................................................................77 
A Description of the Problem....................................................................................................................77 
Getting Started.........................................................................................................................................78 
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Starting A New Job – The Simulate Flowsheet Window...........................................................................80 
Selecting Engineering Units......................................................................................................................82 
Drawing the Flowsheet.............................................................................................................................83 
Putting Streams on the Flowsheet............................................................................................................87 
Selecting Components..............................................................................................................................90 
Selecting Thermodynamic Options...........................................................................................................92 
Defining the Feed Streams .......................................................................................................................94 
Inputting Equipment Parameters..............................................................................................................94 
Pot Charge Definition.................................................................................................................94 
Batch Column Specifications......................................................................................................94 
Operation Parameters Specification...........................................................................................94 
Set Screen Information Specifications........................................................................................94 
Operation Step Commands........................................................................................................95 
Insert Operation Specifications...................................................................................................95 
Delete Operation Step Specifications.........................................................................................95 
Copy Operation Step Specifications...........................................................................................95 
Specifying the Pot Charge Composition and Condition............................................................................95 
Specifying the Column Configuration........................................................................................................97 
Defining the Operating Steps....................................................................................................................98 
Operating Step 1 .......................................................................................................................98 
Operating Step 2 .....................................................................................................................102 
Operating Step 3 .....................................................................................................................103 
Operating Step 4 .....................................................................................................................105 
Operating Step 5 .....................................................................................................................106 
Runtime Information.................................................................................................................107 
Running the Simulation...........................................................................................................................108 
Reviewing the Results Interactively........................................................................................................110 
Plotting the Results.................................................................................................................................110 
Reviewing Batch Results........................................................................................................................113 
Generating a Full Report........................................................................................................................113 
Summary................................................................................................................................................114 
CHEMCAD USER’S GUIDE...................................................................................................................115 
Setting Up a Steady State Simulation – An Overview.............................................................................115 
Step 1:  Starting a New Job......................................................................................................116 
Step 2:  Selecting Engineering Units........................................................................................116 
Step 3:  Creating a Flowsheet..................................................................................................117 
Step 4:  Selecting Components................................................................................................117 
Step 5:  Selecting Thermodynamic Options.............................................................................118 
Step 6:  Inputting Feed (and Cut) Stream Data........................................................................119 
Step 7:  Specifying Unit Operations..........................................................................................120 
Step 8:  Running the Simulation...............................................................................................120 
Step 9:  Reviewing the Results.................................................................................................121 
Step 10 Producing Reports and PFD’s.....................................................................................121 
Coach.....................................................................................................................................................121 
Getting Started........................................................................................................................................122 
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How to Start a New Job  ....................................................................................................................124 
Briefly.......................................................................................................................................124 
Details......................................................................................................................................125 
How to Select Flowsheet Engineering Units...........................................................................................126 
Resetting Current Units to a Predefined Profile........................................................................126 
Edit Current Engineering Units Profile......................................................................................127 
Create a Default Engineering Units Profile...............................................................................128 
Create a User Engineering Units Profile..................................................................................128 
Graphics Commands – An Overview.....................................................................................................129 
Drawing Flowsheets in the Edit Flowsheet Mode.....................................................................129 
Graphics Features of the Plot Window.....................................................................................130 
Using the PFD Window............................................................................................................130 
The Edit Flowsheet Mode.......................................................................................................................131 
The Main Palette ...................................................................................................................................131 
Sub-Palettes.............................................................................................................................133 
The Size and Shape of the Palettes.........................................................................................134 
Hiding and Calling the Palettes................................................................................................134 
Moving the Palettes..................................................................................................................135 
Drawing With the Palette........................................................................................................................135 
Drawing Lines..........................................................................................................................135 
Drawing Rectangles.................................................................................................................135 
Drawing Ellipses.......................................................................................................................136 
Drawing Multi-lines...................................................................................................................136 
Drawing Polygons....................................................................................................................136 
How to Put Text on a Drawing................................................................................................................137 
The Format Command...........................................................................................................................137 
Bring to Front...........................................................................................................................138 
Send to Back............................................................................................................................138 
Fill Pattern................................................................................................................................138 
Pen Style..................................................................................................................................139 
Arrowheads..............................................................................................................................139 
Color........................................................................................................................................139 
The Pen/Text Color..................................................................................................................139 
Font..........................................................................................................................................140 
Align.........................................................................................................................................140 
Import Bitmap...........................................................................................................................140 
How to Rotate an Object Using the Palette............................................................................................141 
How to Move, Modify, Delete, or Flip Objects.........................................................................................141 
Moving a Single Object............................................................................................................141 
Moving Multiple Objects...........................................................................................................141 
Panning the Flowsheet.............................................................................................................141 
Resizing ...................................................................................................................................142 
Deleting ...................................................................................................................................142 
Flipping an Object’s Y-Axis......................................................................................................142 
How to Copy to the Clipboard.................................................................................................................142 
Using the Metafile....................................................................................................................142 
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Using the Copy Command.......................................................................................................142 
How to Generate a DXF File...................................................................................................................143 
How to Draw a Flowsheet.......................................................................................................................143 
Step 1: Enter the Edit Flowsheet Mode....................................................................................143 
Step 2: Place UnitOps on the Flowsheet..................................................................................146 
Step 3: Connecting UnitOps with Streams...............................................................................146 
Step 4: Modifying and Adding to the Flowsheet.......................................................................147 
How to Add UnitOps to the Flowsheet....................................................................................................148 
Briefly.......................................................................................................................................148 
Details......................................................................................................................................148 
How to Copy UnitOps on the Flowsheet.................................................................................................149 
Briefly.......................................................................................................................................149 
Drawing Streams....................................................................................................................................149 
Drawing Simple Streams (One or Less Direction Change).......................................................151 
Drawing Complex Streams (Multiple Direction Changes).........................................................151 
How to Select Components for the Component List...............................................................................151 
Calling the Component List Dialog Box..................................................................................................152 
Using the Component List Dialog Box....................................................................................................152 
Briefly.......................................................................................................................................153 
Details......................................................................................................................................153 
How to Select K-Value Options..............................................................................................................154 
Briefly.......................................................................................................................................154 
Details......................................................................................................................................155 
How to Select Enthalpy Options.............................................................................................................157 
Briefly.......................................................................................................................................157 
Details......................................................................................................................................158 
How to Define the Feed Streams............................................................................................................159 
Briefly.......................................................................................................................................159 
Details......................................................................................................................................160 
How to Specify Unit Operations..............................................................................................................161 
Calling a UnitOp Dialog Box.....................................................................................................162 
Rules for Completing the UnitOp Dialog Boxes........................................................................162 
Degrees of Freedom and UnitOp Dialog Boxes.......................................................................162 
How to Run Simulations in CHEMCAD Suite.........................................................................................162 
Running Steady State Simulations...........................................................................................163 
Converge Settings....................................................................................................................165 
How to Review Stream Compositions.....................................................................................................167 
Selecting Streams....................................................................................................................167 
How to Set Flow Units for Results and Reports......................................................................................168 
How to View Stream Properties Using the Results Command...............................................................168 
Using the Properties Option Dialog Box...................................................................................169 
How to Plot.............................................................................................................................................169 
Plot Menu Options....................................................................................................................170 
How to Create Reports...........................................................................................................................187 
Calculate and Give Results......................................................................................................188 
Report Formats........................................................................................................................188 
vi 
Select Streams.........................................................................................................................188 
Select Stream Properties.........................................................................................................191 
Stream Flowrate/Composition..................................................................................................191 
Distillation Summaries..............................................................................................................192 
Heating Curves........................................................................................................................193 
Batch/Dynamic Results............................................................................................................193 
Miscellaneous..........................................................................................................................194 
End Report...............................................................................................................................194 
How to Create PFD’s..............................................................................................................................195 
Creating the Main PFD.............................................................................................................195 
Creating Secondary PFD’s.......................................................................................................196 
Opening and Editing Secondary PFD’s....................................................................................197 
Adding a Stream Databox to the PFD....................................................................................................197 
Step 1: Select the Streams to be Included in the Databox.......................................................198 
Step 2: Complete the PFD Properties Options Dialog Box......................................................198 
Step 3: Complete the Databox Settings Dialog Box.................................................................200 
Step 4: Move and Stretch the Databox....................................................................................200 
Adding a UnitOp Databox to a PFD........................................................................................................200 
Step 1: Select the UnitOps for Databox Generation.................................................................201 
Step 2: Complete the Databox Settings Dialog Box.................................................................201 
Step 3: Move and Stretch the Databox....................................................................................202 
Adding a TP Box to a PFD ....................................................................................................................202 
Adding an Excel Range..........................................................................................................................204 
Running a Dynamic Simulation..............................................................................................................205 
The Steps for Setting Up a Dynamic Flowsheet.......................................................................205 
Starting a New Job...................................................................................................................206 
Selecting Engineering Units.....................................................................................................206 
Draw the Flowsheet.................................................................................................................206 
Make Sure the Dynamics Mode is Turned On.........................................................................207 
Select Components..................................................................................................................208 
Select Thermodynamic Options...............................................................................................208 
Specify Feed Streams and Stream Initial Conditions...............................................................208 
Specifying UnitOps...................................................................................................................208 
Specifying Runtimes, Time Steps, and/or Stop Criteria...........................................................208 
Running the Dynamic Simulation.............................................................................................209 
Re-Running and Extending the Run.........................................................................................212 
How to Run a Sensitivity Analysis..........................................................................................................213 
Completing the Independent Variable Dialog Box....................................................................215 
Completing the Recorded Variable Dialog Box........................................................................216 
Using Optimization in CHEMCAD..........................................................................................................216 
How to Build User Added Symbols and Icons........................................................................................221 
Symbol Builder Palette...........................................................................................................................222 
Procedure for Building and Saving UnitOp Icons...................................................................................223 
User Added Palette Names....................................................................................................................225 
vii 
CHEMCAD Version 5.6 
User’s Guide 
GETTING STARTED 
The CHEMCAD software system is a suite of modules operating within a single program but licensed 
individually.  At the present time, the following modules are available within this framework: 
CC-STEADY STATE 
For steady state simulation, physical properties calculations, equipment sizing 
and costing, and certain other chemical engineering calculations. 
CC-BATCH 
For the simulation of batch distillation columns. 
CC-ReACS 
For the simulation of batch reactors. 
CC-DCOLUMN 
For the dynamic simulation of chemical processes including distillation 
columns. 
CC-DYNAMICS  
(CC-ReACS + 
CC-DCOLUMN) 
For the dynamic simulation of chemical processes including reactors and 
distillation columns. 
CC-THERM 
For detailed design/rating/simulation of shell and tube, double pipe, plate frame 
heat exchangers and air coolers. 
CC-FLASH 
For the calculation of mixture physical and thermodynamic properties. 
CC-SAFETY NET 
For the design and analysis of safety relief networks and piping systems in 
general. 
CC-POLYMERS 
For the simulation of polymer reaction systems. 
CC-NETWORK 
For the management of CHEMCAD products on local area networks. 
This User’s Guide describes the basic operating procedures for the entire system, and therefore for all 
ten modules. 
User’s Guide 
CHEMCAD Version 5.6 
HOW TO INSTALL THE CHEMCAD SUITE FOR WINDOWS 
WHAT’S IN THE BOX 
When you open your CHEMCAD package, you should find the following items: 
1.  A CHEMCAD User’s Guide 
2.  One CHEMCAD installation CD  
3.  One CHEMCAD “dongle” or copy protection device.  If you already have a dongle, another one may 
not be shipped.  This dongle must be plugged into the parallel / USB port of your computer in order 
to run the program.  The dongle is not needed for installing the program.   
4.  One licensing disk (to reprogram your dongle) 
FOR LICENSING ARRANGEMENTS USING SYSTEM AUTHORIZATION (UNIVERSITY 
CUSTOMERS) OR LICENSE MANAGER (CORPORATE CUSTOMERS) INSTEAD OF A DONGLE, 
ITEMS (3) AND (4) ABOVE WILL BE OMITTED. 
BASIC REQUIREMENTS 
CHEMCAD is compatible with all Windows systems, including Windows 2000, and XP. While 
CHEMCAD may install on NT 4.0, Win 95 and Win 98, Microsoft no longer supports these operating 
systems, and so neither can Chemstations. 
The hardware requirements: 
• 
Suggested processor: Pentium III equivalent or faster.  While the program will run on 486-
based systems, it will be very slow.  CHEMCAD is processor intensive: simulations will run 
faster on a more powerful processor.  CHEMCAD will run on computers with AMD processors. 
• 
Suggested memory: 128mb of RAM (512 is optimal). Minimum requirement: 32mb.  
• 
The computer should have at least 200 MB of hard drive space available.  
• 
If the computer uses Windows NT/2000/XP, you MUST
log in with administrator 
privileges in order to install CHEMCAD.  See your information services professional for 
details. 
INSTALLING THE CHEMCAD SUITE FOR WINDOWS 
In your package from Chemstations, you will find a CD-ROM. 
1.  Close all programs that are currently running. 
2.  Insert the CHEMCAD CD-ROM into the CD Drive. 
3.  Open the My Computer icon on the Window’s Desktop. 
4.  Open the CD-Rom Disc icon. 
5.  Run the program called Autorun.EXE in the main (root) directory of the CD-ROM. 
The following screen will appear on your desktop: 
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