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8. Hoverthemouseovertheright-mostterminalcarbonandtypetheletter‘o’tocreatetheketonefunctionalgroup.
9. Toconnecttheleftterminalcarbons,selectthesolidbondtoolandclick-dragabondfromonecarbontotheother.
Thestructureiscomplete.
Tutorial3:Fischerprojections
ThistutorialdemonstrateshowtocreateaFischerprojectionofglucose:
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Figure19.2:Fischerprojections
Todrawthefirstbond:
1. ClicktheSolidBondtool.
2. Pointinthedocumentwindow.Dragdownwardtodrawthefirstbond.
3. Pointtotheloweratom,anddragdownwardagaintodrawthesecondbond.
TheredwavyboxappearsbecauseShowChemicalWarningsisselected.Wewillkeepitselectedfornow.
4. Repeatstep3therearefivebonds.
Figure19.3:Drawingthebackbone
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Note:Whenyoudragthepointeralongthelengthofthebonds,thepointeralternatesbetweenanarrowanda
cross.Thearrowindicatesyouarepointingoverthecenterofabond,andthecrossindicatesyouarepointingto
anatom.
Addhorizontalbondstothesecondatominthestringofbondsyoucreated:
1. Toaddahorizontalbond,pointtotheuppermostChemicalWarningboxandclickit.
Notethattheredwavyboxdisappearswhenyouaddabond.
2. Clickagaintoaddahorizontalbondintheoppositedirection.
3. Repeatsteps1and2witheachChemicalWarningboxuntilallhorizontalbondsareadded.
Figure19.4:Addinghorizontalbondstothebackbone
Addlabelstothefirstandlastcarbonatoms:
1. SelecttheTexttool.
2. Clicktheuppermostcarbonatomtocreateatextbox,andtypeCHO.
3. Clickthelower-mostcarbonatom,andtypeCH2OH.
Figure19.5:Addingatomlabels
Addtherepeatinglabelsforthehydrogensandhydroxylgroups:
1. ClicktheatomshowninAbelowandtypetheletterH.
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2. Double-clickeachoftheotheratomslabeledashydrogeninB.
Figure19.6:Addingrepeatingatomlabels
Tip:Doubleclickanatomwiththetexttooltorepeatthelastlabel.
3. ClickoneoftheremainingatomsandtypeO.
4. Double-clicktheremainingatomstorepeatthelabel.
Figure19.7:Completingthedrawing
Viewthebasicpropertiesofthestructureandpastetheinformationintoyourdocument:
1. Clickaselectiontooltoselectthelaststructuredrawn.Ifthestructureisnotselected,double-clickthestructure.
2. GotoView>ShowAnalysisWindow.
3. IntheAnalysiswindow,clickPaste.Theanalysisinformationappearsasacaptionbelowthestructure.
Tutorial4:PerspectiveDrawings
Inthistutorial,weexplainhowtocreateaperspectivedrawingbycreatingamodelof
a
–D–glucoseasaHaworthpro-
jection.
Createanewdocumentusingthedefaultstyle:
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GotoFile>OpenStyleSheets>NewDocument.
Note:Ifyouarefollowingthetutorialsinorder,ChemBioDrawwillrememberyourlastdrawingusedtheACSstyle
sheetandopenitasthedefault.ThisstepresetsthedefaulttoNewDocument.
Drawaring:
1. ClicktheCyclohexaneRingtool.
2. Clickinanemptyareaofadocumentwindow.Acyclohexaneringappears.
Rotatethering:
1. GotoEdit>SelectAll(ortypeCTRL+A).
2. GotoObject>Rotate(ortypeCTRL+R)
3. IntheRotateObjectsdialogbox,enter30degreesforanangleandclickRotate.Thecyclohexaneringrotates.
Changecyclohexanetotetrahydropyran:
1. Clickoutsidethestructuretodeselectit.
2. Pointtotheatominthefigurebelow,andtypethelettero.
Resizehorizontally:
1. GotoEdit>SelectAll(ortypeCTRL+A).
2. Usingaselectiontool,click-dragtherightsidehandletohorizontallyresizethering.Releasethemousebutton
whentheringisstretchedabout200%.
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Enlargethering:
1. GotoEdit>SelectAll(ortypeCTRL+A).
2. Click-dragtheringcorneradjustmenthandletoincreasethesizeoftheringto150%.Adialogboxappears,asking
youwhetheryouwanttoscalethedrawingandtextsettings.
3. ClickNo.
Addverticalbonds:
1. ClicktheSolidBondtool.
2. Pointtotheatomshowninthefigurebelowanddragupwardtocreateabond.
3. Pointtothesameatom,anddragdownwardtocreateanotherbond.
4. Repeatthisprocedurefourmoretimes,addingthepairsofverticalbondsshownbelow:
CreateOHlabels:
YoucanusetherepeatingbondlabeltechniqueinTutorial4,orusehotkeys.FortheHotkeymethod,justpointand
typetheletter"o".TheTexttoolmethodisrepeatedhere,withaslightvariation.
1. SelecttheSolidBondtool,pointtotheatomshowninthefigurebelow,anddouble-clicktoopenatextbox.
2. TypeOH.
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Figure19.8:AddingtheOHlabels
3. Movethepointertotheotheratomsasshown,andtriple-clicktorepeattheatomlabel.
Tip:Ifthedrawingistoosmalltoplacethelabels,gotoView>Magnifytoenlargeit.
AddtheCH
2
OHlabel:
1. Triple-clicktheupperatomofC5.
2. PressENTERtoopentheatomlabeltextbox.TypeCH2beforetheOH.
Changethetypeofthefrontbonds:
1. ClicktheBoldBondtool.
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2. Clickthebondshowninthefigure.
3. Thecursorchangestoaboldarrowasyoupointtothebond.
4. ClicktheWedgebondtool.
5. Clickeachringbondadjacenttotheboldbond.
Foreachbond,pointslightlyoffcenterinthedirectionthatyouwantthewideendofthewedgetobeorientedand
click.
Tip:Ifyoumovethepointertoofar,thehighlightboxdisappears.Ifplacingthepointerisdifficult,gotoView>Mag-
nify.
Note:Ifthewedgeispointedinthewrongdirection,clickthebondagaintoflipitsorientation.
Thefinalstructureis:
Tutorial5:Newmanprojections
ThistutorialdemonstrateshowtodrawaNewmanprojectionofethane:
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Drawethane:
1. ClicktheSolidBondtool.
2. Inthedocumentwindow,click-dragdownwardtocreatethefirstbond.
3. Clicktheatomatthebottomofthebondtoaddasecondbond.
4. Clickthebottomatomagaintoaddathirdbond.
5. Hoverthemouseovertheendofeachbond(withoutclicking)andtypeHtoaddthehydrogenatoms.
Duplicatethestructure:
1. Clickaselectiontool.Thelaststructureyoudrewisselected.
2. Tocreateaduplicate,holddowntheCTRLkeywhiledraggingtheselectionrectangleupwardtotherightoftheori-
ginal.
Theselectionboxdisappearswhileyouaredragging.
Addabondbetweentheduplicatedstructures:
1. ClicktheSolidBondtool.
2. Clickanddragfromthetertiarycarbonatomofthelowerfragmenttotheothertertiarycarbon.
Note:Whenconnectingexistingatoms,theFixedLengthandFixedAnglescommandsareignored.
Whenyoureleasethemousebutton,theethanestructureiscomplete.Now,createitsNewmanprojection.
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DrawingtheNewmanprojection
Inthisstep,youdrawthehollowcirclethatisparticulartoNewmanprojections.
1. ClicktheOrbitaltool,andselectthes(Open)orbital.
2. Pointtotheleftcentercarbonandclick-dragoutward.
Thesizeoftheorbitalisconstrainedjustasbondsare.TheconstraintisbasedonapercentageoftheFixedLength
settingintheDrawingtaboftheDocumentsettingsdialogbox.
Note:Orbitalsarenotautomaticallygroupedwiththestructure.Togrouptheorbitalwiththeexistingstructureso
youcanmovethemtogether,gotoObject>Group.
1. ClicktheMarqueetool.Theorbitalisselected.Clickanemptyspacetodeselectit.
2. Pointabovethestructureanddragaroundtheupperfragmenttoselectthethreebonds.Donotselectthebondcon-
nectingthetwofragments.
Rotatetheselection:
1. Double-clicktherotationhandletoopentheRotateObjectsdialogbox.
2. Type180intheAngletextboxandclickRotate.
Withtherotatedbondsstillselected,changethestructurelayeringsothattheselectionisinfront.
3. GotoObject>BringtoFront(thereisnovisiblechangewhenyoudothis).
MovethefrontpartofthestructuretocreateaNewmanprojection:
1. PointwithintheSelectionRectanglesothepointerchangestoahand.
2. Dragtheselectionuntilthetertiarycarboniscenteredwithintheorbital:
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