display pdf from byte array c# : Rotate pdf pages by degrees Library control component .net azure html mvc ChemBioDraw%20v14%20User%20Guide6-part1470

Asp
BzOM
Cy
DMTr
Gly
m-Phenylene
Benzoyl
c-C3H5
cyclobutyl
DNP
His
m-Tolyl
Benzyl
c-C4H7
cycloheptyl
Dnp
i-Am
MDIPS
Bn
c-C5H9
cyclooctyl
Dns
i-Bu
MDPS
Boc
c-C6H11
cyclopentyl
DNS
i-C3H7
Me
MEM
n-Pr
Phenyl
s-Butyl
TBDMS
Thr
Mes
N3
Pht
s-C4H9
TBDPS
TIPDS
Met
neo-Am
Piv
s-C5H11
TBMPS
TIPS
MMTr
neo-C5H11
PMB
SEM
TBS
TMS
MOM
Np
PMBM
Ser
TDS
Tos
MPM
o-C6H4
PNB
SES
Tf
trans-Cin-
namyl
Ms
o-Phenylene
Poc
t-Am
Tfa
Troc
MTM
o-Tolyl
PPi
t-BOC
TFA
Trp
n-Am
p-C6H4
Pr
t-Boc
Thexyl
Trt
n-Bu
p-Phenylene
Pro
t-Bu
THF
Ts
n-C3H7
p-Tolyl
Pv
t-Butyl
Thf
Tyr
n-C4H9
Ph
s-Am
t-C4H9
THP
Val
n-C5H11
Phe
s-Bu
t-C5H11
Thp
Xyl
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Basic Drawings
ChemBioDrawprovidesavarietyoftoolsfordrawingeverythingfromsimplechemicalstructurestocomplexreac-
tions.Inthissection,weintroducebasictechniquestohelpyoucreateyourfirststructures.Wealsoexplainhowto
addfeatures,suchasarrowsandshapes,toenhancestructuresandreactions.Formoredrawingfeatures,see
"BioDraw(Ultrafeatureonly)"onpage92and"AdvancedDrawingTechniques"onpage118.
Bonds
TheMaintoolbarandMultipleBondstoolbaroffernumerousoptionsfordrawingbonds.Sometoolsarefordrawing
specifictypesofbonds,whileothersarefordrawingstructuresfordatabasequeries.Foradditionalinformationonvari-
ousbondtypes,see"BondConventions"onpage278.
DrawingBonds
Todrawthefirstbondofyourstructure,selectthesolidbondtoolintheMaintoolbarandclickinthedocumentwin-
dow.Thebondappearsinthedrawingwindow.Todrawanotherbondattachedtothefirst,clickeitherendofthefirst
bond.Thesecondbondappearsinthedrawingwindow,asshownbelow.
Figure6.1:Addingabondtoanatom
Youcandrawabondinanydirection.Usingabondtool,clickanddragfromanexistingatomoranemptyareainthe
documentwindow.Thebondisdrawninthedirectionyoudragthecursor.
Figure6.2:Addingabondbydragging
DoubleBonds
Therearefourwaystodrawadoublebond:
DrawabondusingtheDoublebondtool.
Drawasinglebondoveranexistingsinglebond.
Usinganybondorselectiontool,pointtoanexistingbondandtype‘2’.See"ShortcutsandHotkeys"onpage44.
Right-clickanybondandselectDouble>Plaininthecontextmenu.
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DoubleEitherBonds
Doubleeitherbonds,orcrosseddoublebonds,indicateunspecifieddoublebondconfiguration,oramixtureofcon-
figurations.Todrawadoubleeitherbond,usethedoubleeitherbondtool
fromtheMultipleBondstoolbar,or:
1. DrawabondusingtheWavyBondtool.
2. Clickthecenterofthebondtocreateadoublebond.
3. Clickagaintocreateadoubleeitherbond.
TripleBonds
Therearethreewaystodrawatriplebond:
DrawabondusingtheTripleBondtool.
UsingtheSolid,Dashed,orBoldBondtool,dragfromoneendofanexistingdoublebondtotheotherend.
Usinganybond,orselectiontool,pointtoanexistingbondandtype‘3’onyourkeyboard.
QuadrupleBonds
Therearethreewaystodrawaquadruplebond:
DrawabondusingtheQuadrupleBondtool.
UsingtheSolid,Dashed,orBoldBondtool,dragfromoneendofanexistingtriplebondtotheotherend.
Usinganybondorselectiontool,pointtoanexistingbondandtype‘4’onyourkeyboard.
Tochangeaquadruplebondintoasinglebond:
1. Selectanybondtool.
2. Dragfromoneendofanexistingquadruplebondtotheother.
Youcanalsodrawmultiplebondsbyright-clickingabondandselectingthebondtypefromtheshortcutmenu,using
thebondpropertiesdialog,orusingHotkeys.See"BondProperties"onpage239.
Note:Toreducethebondorder,selecttheErasertoolandclickthebond.
DativeBonds
Dativebondsareaspecifictypeofcovalentbondinwhichthepairofelectronssharedbytheatomsintheformation
ofabondiscontributedbyoneoftheatomsonly.Theatomcontributingthepairofelectronsisknownas"donor"
whiletheatomwhichdoesnotcontribute,butsharesthepairofelectrons,isreferredtoas"acceptor".
Todrawadativebond:
1. SelecttheDativeBondtool.
2. Dragfromthepositivetothenegativeend(arrowhead)ofthedativebond.
Dativebondsaredrawnwithafixedorientationinadocumentwindow.
Tochangetheorientationofadativebond:
Clickthebondusingthedativebondtool.
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WedgedBonds
Todrawawedgedbond:
1. Clickoneofthewedgedbondtools.
2. Dragfromthenarrowendofthewedgedbondtothewideendofthewedgedbond.
Wedgedbondsaredrawnwithafixedorientationinadocumentwindow.
Tochangetheorientationofthewedgedbond:
Clickthebondusingthewedgedbondtool.
Note:ChemBioDrawtreatshashedwedgedbondswiththenarrowendintheplaneofthescreenandthewideend
behindtheplane.
ChangingBonds
Youcanchangebondsby:
Changingbondtypes
Changingbondalignmentandorientation
Movingatoms
Layeringbonds
ChangingBondTypes
Changeasinglebondfromonetypetoanotherusingoneofthefollowingmethods:
Selectabondtoolandclickanexistingbond
Right-clickandselectthenewtypefromthecontextmenu
Withhotkeys.See"ShortcutsandHotkeys"onpage44.
ChangingDoubleBonds
Tochangeonetypeofdoublebondtoanother:
1. SelecttheBold,Dashed,orSolidBondtool.
2. Clickadoublebond.
Thedoublebondchangestothenewbondtype.Oneofthebondsinthedoublebondisalwaysasolidordashedbond.
Note:Ifyouclickatautomericbond(solid/dashed)againwiththedashedbondtool,youcreateanaromaticdouble
bond(dashed/dashed).
AligningDoubleBonds
Doublebondscanhaveoneofthreealignmentsrelativetootherbonds—above,below,andcentered.
Above
Below
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Centered
1. Clickthebondtoolusedtocreatetheexistingdoublebond.
2. Tochangethealignment,dooneofthefollowing:
Clickthecenterofthedoublebond.
Right-click,pointtoBondPositiononthecontextmenu,andchoosethealignment.
MovingAtoms
Tomoveanatominastructure,clickanddragitusingaselectiontool.Tomovetwobondedatomsinastructure,
clickanddragthebondbetweenthem.
Tomoveindividualatoms:
1. Clickaselectiontool.
2. Pointtotheatomyouwanttomove.Ahighlightboxappearsovertheatom.
3. <SHIFT>+dragtheatom.
Note:Youcanalsomoveatomsusingaselectiontool.See"MovingObjects"onpage83.
ReducingRingSize
Youcanreducethenumberofatomsinaring.Forexample,youcanconvertcyclohexanetocyclopentane.
Toreducetheringsize,dooneofthefollowing:
Usingtheselectiontool,clickanddrag.
Usingabondtool,pointtoanatomand<SHIFT>+drag.Releasewhenoneatomisontopoftheother.Thebond
betweentheatomsdisappears.
BondCrossing
Whenonebondcrossesanother,youcanindicatewhichbondisinfront.Thebondwhichisbehindhasasmallsec-
tioncutout,soyoucanclearlydiscernwhichbondisfront-most.
Tomoveanobjecttothefrontposition:
1. Selecttheobjecttomovetothefront.
2. GotoObject>BringtoFront.Theselectedobjectnowappearsinfrontofallotherobjects.
Similarly,navigatetoObject>SendtoBacktopositionthebondbehindotherobjects.
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Note:Somefileformatsstore3Dcoordinatesforatoms,whileothersonlystore2Dcoordinates.Forbondswith
3Dcoordinates,thosecoordinatesdeterminethevisiblebondcrossings.BringToFrontandSendToBack
havenoeffect.Formoredetailsonconvertingbondsandstructuresinto3Dview,see"3DViewing"onpage165
FixedBonds
Bydefault,ChemBioDrawdrawsstructureswithfixedbondlengthsandbondangles.Thevaluesofthoselengthsand
anglesisdeterminedbythesettingsfortheparticulartypeofdocument.Formoreinformation,see"DocumentSet-
tings"onpage38.However,youcanmodifythebehaviorsothatyouarenotconstrainedtofixedbondsandangles.
Note:Tosuppressfixedlengthsandfixedangles,presstheALTkeyasyoudragthebond.
DrawingFixedLengthBonds
Todrawbondsconstrainedtoafixedlength:
1. NavigatetoObject>FixedLengthsandensureacheckmarkappearsnexttoFixedLengths.
2. Drawabondusinganybondtool.
DrawingFixedAngleBonds
Bondanglesaregenerallyeithersettothedefaultchainangleof120degrees,orareconstrainedtoanglesof15
degreeincrements.
Todrawfixedanglebonds:
1. NavigatetoObject>FixedAnglesandensureacheckmarkappearsnexttoFixedAngles.
2. Drawabondusinganybondtool.
Thebondsinthenewstructureappearatstandard120°angles.
ChangingFixedValues
Bydefault,bondlengthsare.4176inchesandbondanglesinachainare120°.
Tochangefixedvalues:
1. NavigatetoFile>DocumentSettingsandclicktheDrawingcategory.
2. EnteravalueintheFixedLengthtextfield.Usein,cm,pt,orpicasforunits.
3. EnteravalueintheChainsAngletextfield.
4. ClickOK.
Formoreinformationondrawingsettings,see"DrawingSettings"onpage24.
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Atoms
Bydefault,whenyoudrawstructureswiththevariousbond,ring,orchaintools,simplehydrocarbonsarecreated.
YoucanaddatomlabelstotheatomsusingtheTexttool.YoucanalsousetheTexttooltoaddtextualcaptionstoa
document.Forexample,youcanaddtheatomlabel“OH”toadrawingoftoluenetocreatephenol:
1. Drawthetoluenestructure.
2. UsingtheTexttool,clickthemethylcarbon.Atextfieldappears.
3. TypeOHinthetextfield.
4. Clickoutsidethetextfield.
Toedittheatomlabel,clickinthetextfieldwiththetexttoolandbegintyping.
Youcaneitherentertheatomlabelinatextfieldortypethehotkeywhilehoveringoveranatom.Formoreinformation
abouthotkeys,see"Hotkeys"onpage61and"ShortcutsandHotkeys"onpage44.
PeriodicTable
Youcanusetheperiodictabletoinsertatomsintostructures.NavigatetoView>ShowPeriodicTableWindow.
ClickasymbolintheperiodictabletohighlighttheatomandactivatetheTexttool.Movethemouseacrossthetable
tohighlighteachatom.
Toaddanatom.Selectthedesiredelementintheperiodictableandclickanemptyspaceinthedocument.The
atomappearsinitschemicallyneutralform.Forexample,carbonappearsasCH
4
andhydrogenappearsasH
2
.
Tolabelanatom.Clickanexistingunlabeledatom.
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Tochangetheoxidationstate.Usingthesymbolfortheatom,clicktheatominthedocumentwindow.
Tochangetoadifferentatom.Selectthenewatomintheperiodictableandclicktheatominthedrawingyouwant
tochange.
Toeditalabel.YoucaneditanatomlabelusingtheTexttool.Highlightthetextandclickasymbolintheperiodic
table.Thehighlightedtextisreplaced.
RepeatingAtomLabels
Youcanrepeatanatomlabelusingthetext,bond,orringtools.
1. ClicktheTexttool.
2. Labelasingleatom.
3. Dooneofthefollowing:
UsingtheTexttool,double-clickanotheratom.
Usingabond,ring,oracyclicchaintool,triple-clickanotheratom.
DeletingLabels
Todeleteanatomlabel,dooneofthefollowing:
SelecttheErasertoolandclicktheatomlabel.
Withaselection,bond,orringtoolselected,pointtotheatomlabelandpressthe<spacebar>,<Backspace>,or
<Delete>key.Notethatifanatomislabeled,pressingthe<spacebar>,<Backspace>,or<Delete>keywilldelete
thelabel,butnottheatom.Todeletetheatomaswell,pressthe<Delete>keyasecondtimetodeletethe
unlabeledatom.
Captions
YoucanaddandeditcaptionstoyourstructuresusingtheTexttool.Thefollowingexampleaddsthecaption'Phenol'
toaphenolstructure.
Toaddthecaption‘Phenol’toaphenolstructure:
1. Drawthephenolstructure.
2. UsingtheTexttool,clickbelowthedrawingandtype“Phenol”inthetextfield.
3. Clickoutsidethetextfield.
Toeditthecaption,clickinthetextfieldwiththeTexttoolandbegintyping.Formoreinformation,see"NewLinesand
ClosingTextBoxes"onpage21.
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Formatting
Eachnewcaption,oratomlabel,usesdefaultdocumentsettingsforfont,size,andstyleofcaptionsandatomlabels.
Youcanchangetheformatby:
Changingthedocumentsettingsforsubsequentdrawingsinthecurrentdocument.
ChoosinganewformatforanindividualcaptionorlabelfromtheTextmenuortoolbarbeforeyoutype.
Selectingtextandapplyinganewformattoanindividuallabelafteryoutype.
Tospecifythetextsettingsfornewcaptionsandatomlabelsinthecurrentdocument:
1. NavigatetoFile>DocumentSettings.TheDocumentSettingsdialogappears.
2. SelectTextCaptionsorAtomLabelscategory.
3. Selecttheappropriateoptions.
4. ClickOK.Thesesettingsaffectallnewcaptions,oratomlabels,inthecurrentdocument.
Youcansetthetextformatforanindividualcaption,oratomlabel,beforeyoubegintyping.
Tosetthetextformatbeforeyoutype:
1. ClicktheTexttoolandclickinthedocumentwindow.Atextfieldappears.
2. Setthetextformatinoneofthefollowingways:
FromtheTextmenu,choosetheformatoptions.
FromtheStyletoolbar,choosetheformatoptions.
3. Typethetextinthetextbox.
Note:Theformatchangeisappliedtothecurrenttextonly.Anysubsequenttextyoutypeisformattedaccording
tothedefaultdocumentsettingsforthecurrentdocument.
Tospecifyafont,style,andsizeforselectedtext,dooneofthefollowing:
ChoosethefontandsizefromtheTextmenu.
Right-clickandchoosethefontandsizefromthecontextmenu.
FromtheStyleToolbar,selectthefontandsizefromthedrop-downmenus.
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ColoringText
Youcancolorcaptionsandatomlabelsbeforeorafteryoutypethem,andasawholeorinpart.
Tocoloracaptionoratomlabel:
1. SelecttheTexttool.
2. Clickinsidethedocumentwhereyouwanttoplacethetext.
3. ChooseacolorfromtheColormenu.
4. Typethecaptionoratomlabel.
Tocolorindividualcharacters:
1. Selectpartofanexistingcaption,oratomlabel,usingtheTexttool.
2. FromtheColormenu,chooseacolor.
Tocolorseveralcaptionsoratomlabelsatonce:
1. Selectthecaptionsorlabelsusingaselectiontool.
2. ChooseacolorfromtheColormenu.
CaptionWidth
Toeditthewidthofacaption:
1. SelectthecaptionusingtheTexttool.Aresizehandleappearsontherightsideofthecaption.
2. Dragtheresizehandletochangethewidthofthecaption.
AboutFonts
ChemBioDrawusesthefontsinstalledonyourcomputer.IfaChemBioDrawdocumentcontainsfontsthatarenot
availableonaparticularcomputer,theyaresubstitutedwiththeavailablefonts.
CharacterMap
Thefloatingcharactermapwindowdisplaysthe256ASCIIcharactersinanyfont.ThedefaultfontisSymbol.
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